Measurement of the e+e- -->pi+pi- J/psi cross section via initial-state radiation at Belle

The cross section for e(+)e(-)-->pi(+)pi(-)J/psi between 3.8 and 5.5 GeV/c(2) is measured using a 548 fb(-1) data sample collected on or near the Upsilon(4S) resonance with the Belle detector at KEKB. A peak near 4.25 GeV/c(2), corresponding to the so called Y(4260), is observed. In addition, there is another cluster of events at around 4.05 GeV/c(2). A fit using two interfering Breit-Wigner shapes describes the data better than one that uses only the Y(4260), especially for the lower-mass side of the 4.25 GeV enhancement.     

Teaching the substitutive conception of the equals sign

A cumulative body of research has shown that children typically shift from an operational to a relational conception of the equals sign as they move through schooling. Jones (2008) argued that a truly relational conception of the equals sign comprises a substitutive component and a sameness component. Here we present two studies that build on this argument. The first investigated how the equals sign is typically presented to primary children in England, and we report that in the main an operational conception seems to be promoted. The second study measured the impact of a specially designed intervention on early secondary children's conceptions of the equals sign. Pre- and post-test data revealed that the intervention promoted substitutive and sameness components of symbolic equivalence. We consider the theoretical and pedagogical implications of the results.     

Photopolymerization of mixed monolayers and black lipid membranes containing gramicidin A and diacetylenic phospholipids

We formed monolayers and black lipid membranes (BLMs) of photopolymerizable lipids mixed with the channel-forming protein gramicidin A to evaluate their miscibility and the potential for improved stability of the BLM scaffold through polymerization. Analyses of surface pressure vs area isotherms indicated that gramicidin A dispersed with three different synthetic, polymerizable, diacetylene-containing phospholipids, 1,2-di-10,12-tricosadiynoyl-sn-glycero-3-phosphocholine (DTPC), 1,2-di-10,12-tricosadiynoyl-sn-glycero-3-phosphoethanolamine (DTPE), and 1-palmitoyl-2,10,12-tricosadiynoyl-sn-glycero-3-phosphoethanolamine (PTPE) to form mixed monolayers at the air-water interface on a Langmuir-Blodgett (LB) trough. Conductance measurements across a diacetylenic lipid-containing BLM confirmed dispersion of the gramicidin channel with the lipid layer and demonstrated gramicidin ion-channel activity before and after UV exposure. Polymerization kinetics of the diacetylenic films were monitored by film pressure changes at constant LB trough area and by UV-vis absorption spectroscopy of polymerized monolayers deposited onto quartz. An initial increase in film pressure of both the pure diacetylene lipid monolayers and mixed films upon exposure to UV light indicated a change in the film structure. Over the time scale of the pressure increase, an absorbance peak indicative of polymerization evolved, suggesting that the structural change in the lipid monolayer was due to polymerization. Film pressure and absorbance kinetics also revealed degradation of the polymerized chains at long exposure times, indicating an optimum time of UV irradiation for maximized polymerization in the lipid layer. Accordingly, exposure of polymerizable lipid-containing black lipid membranes to short increments of UV light led to an increase in the bilayer lifetime.     

Oscillating gradient measurements of fast oscillatory and rotational motion in the fluids

We demonstrate the combination of oscillating gradient waveforms with single-point imaging techniques to perform measurements of rapidly oscillating and/or rotating fluid motion. Measurements of Fourier components of motion can be performed over a wide range of frequencies, while the immunity of single-point imaging to time-evolution artefacts allows applications to systems with great susceptibility variations. The processing approaches, displacement resolution, and the diffusive attenuation are analyzed. Measurements of high-speed flow rotation in a spiral phantom, periodic displacements of oscillating gas in a thermoacoustic device and of cavitating liquid reveal a variety of motion spectra. The potential systems for study with the technique include turbulent motion, cavitation, and multiphase flows in general.     

Acid catalyzed fullerenation of carbazole polymer

A new homogeneous fullerenated carbazole polymer has been synthesized, revealing a new substitution pattern for carbazole and a new photodecomposition-resistant substitution pattern for fullerenes. The synthetic method may be accomplished in one pot via acid catalyzed alkylation. The new polymer has several unusual photovoltaic, charge storage, and photoconductivity capabilities. © 1994 John Wiley & Sons, Inc.     

The determination of uranium in aqueous samples by means of a pulsed-source fluorescence spectrometer

Luminescence from aqueous uranyl ions is examined by means of a fluorescence spectrometer with a pulsed xenon light source. Background fluorescence is reduced by using time-based discrimination of the uranyl emission, but interference can still occur from quenchers such as iron(III). Such interferences are reduced by extraction of the uranyl ion into hexane containing trin-n-butyl phosphate, with back-extraction into dilute phosphoric acid before measurement. A detection limit of 5 ng ml^?1 is found with a linear calibration range of 0–10 μg ml^?1.     

Fullerenated carbazole polymers via bromination

Surface-substituted and homogeneous fullerenated polymers were produced by bromination followed by a Friedel-Crafts reaction. Control over bonding patterns was provided by the bromination, which enabled the production of photodegradation-resistant fullerenated polymers. © 1994 John Wiley & Sons, Inc.     

The formation and evolution of fractal structure within chaotic attractors

In this paper we examine in detail the formation and evolution of fractal structure in the chaotic attractors of nonlinear dynamical systems. We explicitly obtain the fractal structure of the underlying chaotic attractors of low-dimensional systems and study their evolution as a system parameter is varied. Using periodic enumeration, dimensional, andf() spectral techniques, we obtain a detailed characterization of the multifractal structure.     

Asymptotically (in)dependent multivariate maxima of moving maxima processes

Smith and Weissman introduced a M4 class of processes which are very flexible models for temporally dependent multivariate extreme value processes. However all variables in these M4 models are asymptotically dependent and what this paper does is to extend this M4 class in a number of ways to produce classes of models which are also asymptotically independent. We shall study properties of the proposed models. In particular, asymptotic dependence indexes, coefficients of tail dependence, and extremal indexes are derived for each case.     

Synthetic ligands for apo-neocarzinostatin

Neocarzinostatin (NCS) is a 1:1 complex of an enediyne chromophore (NCSChrom), non-covalently bound to an 11 kDa protein (apoNCS). We are exploring apoNCS as a generic protein system for sequestering small molecules for therapeutic applications. Here, we disclose a new flavone ligand 1 for apoNCS and present a high-resolution NMR structure of this ligand bound to apoNCS. This is the first high-resolution structure of a completely non-cognate ligand bound to the apoNCS protein. This work provides unambiguous evidence that a completely new class of ligand can bind specifically to apoNCS. Furthermore, the mode of binding is different than that of the naphthoate-based ligands, and for such a simple hydrophobic compound, the new ligand surprisingly binds specifically. This work indicates that apo-Neocarzinostatin has multiple selective and distinct binding modes for small-molecule cargo.